Studies on ion-association: thiocyanate ion-pairs of Al(III), Ga(III) and In(III)

Das, R. C. ; Dash, A. C. ; Mishra, J. P. (1968) Studies on ion-association: thiocyanate ion-pairs of Al(III), Ga(III) and In(III) Journal of Inorganic and Nuclear Chemistry, 30 (9). pp. 2417-2423. ISSN 0022-1902

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...

Related URL: http://dx.doi.org/10.1016/0022-1902(68)80252-0

Abstract

The thermodynamic instability constants of GaSCN++ and InSCN++ were determined by spectrophotometry and potentiometry. AlSCN++ could not be detected in solution in the concentration range in which the present work was done. The stabilities follow the order In > Ga > Al. Possible explanation for the sequence has been given.

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