Steric aspects of the oxidation of thioketones by singlet oxygen

Ramnath, Narayan ; Jayathertha Rao, Vaidhya ; Ramesh, Varadaraj ; Ramamurthy, Vaidhyanathan (1982) Steric aspects of the oxidation of thioketones by singlet oxygen Chemistry Letters, 11 (1). pp. 89-92. ISSN 0366-7022

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Official URL: https://www.jstage.jst.go.jp/article/cl1972/11/1/1...

Related URL: http://dx.doi.org/10.1246/cl.1982.89

Abstract

Singlet oxygen oxidation of dialkyl thioketones yields the corresponding ketones and in some cases sulfoxides in varying amounts. Steric considerations on the reactive zwitterionic/diradical intermediates have been invoked to rationalise the product distribution.

Item Type:Article
Source:Copyright of this article belongs to Chemical Society of Japan.
ID Code:90065
Deposited On:04 May 2012 14:25
Last Modified:19 May 2016 04:24

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