Sivaguru, J. ; Jockusch, Steffen ; Turro, Nicholas J. ; Ramamurthy, V. (2003) Photoisomerization of 2, 3-diphenylcyclopropane-1-carboxylic acid derivatives Photochemical & Photobiological Sciences, 2 (11). pp. 1101-1106. ISSN 1474-905X
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Official URL: http://xlink.rsc.org/?doi=b306337m
Related URL: http://dx.doi.org/10.1039/B306337M
Abstract
Contrary to what is known about cis-1,2-diphenylcyclopropane and its derivatives, we find that they have triplet energies of ca. 311 kJ mol-1, do not undergo intersystem crossing upon direct excitation, undergo the less common adiabatic photoisomerization to the corresponding trans isomers, and show emission from excited 1,3-diradical intermediates.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 90063 |
| Deposited On: | 04 May 2012 14:32 |
| Last Modified: | 04 May 2012 14:32 |
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