Formation of rearrangement product in photolysis of α,α-dimethyldeoxybenzoin upon cyclodextrin complexation

Pitchumani, K. ; Ramamurthy, V. (1994) Formation of rearrangement product in photolysis of α,α-dimethyldeoxybenzoin upon cyclodextrin complexation Photochemistry and Photobiology, 59 (4). pp. 399-401. ISSN 0031-8655

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Official URL: http://onlinelibrary.wiley.com/doi/10.1111/j.1751-...

Related URL: http://dx.doi.org/10.1111/j.1751-1097.1994.tb05054.x

Abstract

Solid-state irradiation of cyclodextrin complexes of α,α-dimethyldeoxybenzoin results in the formation of a significant amount of rearrangement product, 4-isopropylbenzophenone, in addition to cage products. This behavior is not observed in the photolysis in solution or in micellar media.

Item Type:Article
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