Tetranuclear homo-and heteroalumoxanes containing reactive functional groups: syntheses and X-ray crystal structures of [{[LAl(Me)](μ-O)(MH2)}2]]

Chandrasekhar, Vadapalli ; Singh, Sanjay ; Kumar, S. Shravan ; Ahn, Hans-Jurgen ; Biadene, Marianna ; Roesky, Herbert W. ; Hosmane, Narayan S. ; Noltemeyer, Mathias ; Schmidt, Hans-Georg (2004) Tetranuclear homo-and heteroalumoxanes containing reactive functional groups: syntheses and X-ray crystal structures of [{[LAl(Me)](μ-O)(MH2)}2]] Angewandte Chemie International Edition, 43 (37). pp. 4940-4943. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...

Related URL: http://dx.doi.org/10.1002/anie.200460395

Abstract

A core with corners: The first alumoxane containing an {Al4O2} core as well as a gallium congener with an {Al2Ga2O2} core are prepared by the reaction of an organoaluminum monohydroxide with MH3NMe3 (see formula; M=Al, Ga; Ar=2,6-iPr2C6H3). These compounds contain reactive hydride groups on the central M2O2 rings and methyl groups on the terminal aluminum atoms.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Aluminum; Alumoxanes; Gallium; Hydrides; Hydroxides
ID Code:8991
Deposited On:29 Oct 2010 12:04
Last Modified:29 Oct 2010 12:04

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