Ray, Sumit K. ; Singh, Pradeep K. ; Singh, Vinod K. (2011) Enantioselective michael addition of malonates to 2-enoylpyridine N-oxides catalyzed by chiral bisoxazoline-Zn(II) complex Organic Letters, 13 (21). pp. 5812-5815. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol202405v
Related URL: http://dx.doi.org/10.1021/ol202405v
Abstract
An enantioselective Michael addition of malonates to 2-enoylpyridine N-oxides catalyzed by a chiral bisoxazoline-Zn(II) complex has been developed. The corresponding Michael adducts have been obtained in high yields with up to 96% ee. A plausible transition-state model has been proposed to explain the stereochemical outcome of the reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 89727 |
| Deposited On: | 30 Apr 2012 14:31 |
| Last Modified: | 30 Apr 2012 14:31 |
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