Chandrasekhar, Vadapalli ; Gopal, Kandasamy ; Nagarajan, Loganathan ; Sasikumar, Palani ; Thilagar, Pakkirisamy (2006) Stannoxanes and phosphonates: new approaches in organometallic and transition metal assemblies Journal of Chemical Sciences, 118 (6). pp. 455-462. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/chemsci/Pdf-Nov2006/455.pdf
Related URL: http://dx.doi.org/10.1007/BF02703942
Abstract
Phosphonate ligands, [RPO3]2-, are extremely versatile in the assembly of multi-tin and multi-copper architectures. We have used organostannoxane cores for supporting multi-ferrocene and multi-porphyrin peripheries. The copper-metalated multi-porphyrin compound is an excellent reagent for facile cleavage of DNA, even in the absence of a co-oxidant. Reaction oft-BuPO3H2 with Cu(C104)2. 6H2O in the presence of 2-pyridylpyrazole (2-Pypz) leads to the synthesis of a decanuclear copper (II) assembly.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Organostannoxanes; Organotin; Multi-ferrocene; Multi-porphyrin; Phosphonates; Pyrazoles |
| ID Code: | 8970 |
| Deposited On: | 29 Oct 2010 12:06 |
| Last Modified: | 16 May 2016 18:51 |
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