Metal alkoxides as versatile precursors for group 4 phosphonates: synthesis and X-ray structure of a novel organosoluble zirconium phosphonate

Chandrasekhar, Vadapalli ; Chakraborty, Debashis ; Bhattacharjee, Manish ; Kratzner, Ralph ; Roesky, Herbert W. ; Noltemeyer, Mathias ; Schmidt, Hans-Georg (2000) Metal alkoxides as versatile precursors for group 4 phosphonates: synthesis and X-ray structure of a novel organosoluble zirconium phosphonate Inorganic Chemistry, 39 (1). pp. 23-26. ISSN 0020-1669

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic9907361

Related URL: http://dx.doi.org/10.1021/ic9907361

Abstract

Reactions of Ph2P(O)(OH) and t-BuP(O)(OSiMe3)(OH) with Ti(O-i-Pr)4 in equimolar ratios gave titanium phosphonates of the type [(O-i-Pr)3Ti(μ -O)2PR1R2]2 (1, R1 = R2 = Ph; 2, R1 = t-Bu, R2 = OSiMe3) as colorless crystalline solids in moderate yields. Reactions of Ph2P(O)(OH) and the isopropoxides of zirconium and hafnium resulted in products of the composition [(O-i-Pr)3M(μ -O-i-Pr)2(μ -OPOPh2)M(O-i-Pr)2]Ph2P(O)(OH) (M = Zr (3), Hf (4)) in high yields. The compounds were characterized by 1H, 31P, and 29Si NMR, infrared (IR), and mass spectroscopic (MS) techniques. The molecular structures of 2 and 3 were confirmed by X-ray crystallography.

Item Type:Article
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Deposited On:28 Oct 2010 10:33
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