Pandey, Mrituanjay D. ; Mishra, Ashutosh Kumar ; Chandrasekhar, Vadapalli ; Verma, Sandeep (2010) Silver-guided excimer emission in an adenine-pyrene conjugate: fluorescence lifetime and crystal studies Inorganic Chemistry, 49 (5). pp. 2020-2022. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic9022008
Related URL: http://dx.doi.org/10.1021/ic9022008
Abstract
This Communication describes a novel adenine-pyrene conjugate (1) and its solid-state structure with silver and copper ions. Single-crystal studies of metal complexes of 1 offer insight into molecular interactions and provide a basis to rationalize possible interactions in the solution state, leading to excimer formation. The robust nature of this interaction was further confirmed by deposition of the silver complex on a graphite surface, which exhibited a remarkable resemblance to its solid-state structure. The structural basis of selective excimer formation in the presence of Ag+ ions presents a viable approach for ratiometric detection of these ions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 8941 |
| Deposited On: | 28 Oct 2010 10:30 |
| Last Modified: | 11 Jul 2012 17:49 |
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