Joshi, Vijaya S. ; Sathe, Kashinath M. ; Nandi, Malay ; Chakrabarti, Pinak ; Sarkar, Amitabha (1995) Severe distortion of π-allyl orientation in a molybdenum complex containing a sterically demanding ligand: crystal structure of hydrotrix(3,5-dimethylpyrazolyl)borato-(π-cinnamyl)-dicarbonyl molybdenum(II) Journal of Organometallic Chemistry, 485 (1-2). C1-C5. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-328X(94)05080-U
Abstract
Steric interaction between terminal allyl substituent and the proximal 3-methyl group of the pyrazole can result in a severe distortion of the π-allyl orientation, as diagnosed by the downfield chemical shift of the central proton of the allyl group and confirmed by the X-ray crystal structure of a π-cinnamyl complex of molybdenum containing hydrotris-(3,5-dimethylpyrazolyl)borate ligand.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Molybdenum; Allyl; Pyrazde; Crystal Structure; Nuclear Magnetic Resonance |
| ID Code: | 89232 |
| Deposited On: | 24 Apr 2012 12:29 |
| Last Modified: | 24 Apr 2012 12:29 |
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