Szarka, Arpad Z. ; Pugliano, Nick ; Palit, Dipak K. ; Hochstrasser, Robin M. (1995) Vibrational coherence in the solution phase photoisomerization reaction of cis-stilbene Chemical Physics Letters, 240 (1-3). pp. 25-30. ISSN 0009-2614
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0009-2614(95)00491-L
Abstract
Coherent low frequency (100-125 cm−1) nuclear motion was detected in the cis → trans condensed phase isomerization of stilbene. A mode, associated with phenyl torsional motion, has a vibrational dephasing time of 100 fs and exhibits solvent-dependent wavepacket dynamics. Selective probe wavelengths (600, 650 and 690 nm) exhibit phase shifts for the wavepacket dynamics that are also solvent sensitive.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 89182 |
| Deposited On: | 30 Mar 2012 10:05 |
| Last Modified: | 30 Mar 2012 10:05 |
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