Chandrasekhar, Vadapalli ; Nagendran, Selvarajan ; Butcher, Raymond J. (1999) Synthesis and characterization of new organosilanediols with Si-N bonds Organometallics, 18 (22). pp. 4488-4492. ISSN 0276-7333
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/om990327c
Related URL: http://dx.doi.org/10.1021/om990327c
Abstract
Using 2,6- and 2,4,6-alkyl-substituted sterically hindered primary amines, N-bonded silicon dichlorides RN(SiMe3)(Si(Me)Cl2) (R = 2,6-Me2C6H3 (1a), R = 2,6-i-Pr-C6H3 (1b) and R = 2,4,6-Me3C6H2 (1c) have been prepared. Controlled hydrolysis of these dichlorides afforded the N-bonded silanediols RN(SiMe3)(Si(Me)(OH)2) (R = 2,6-Me2C6H3 (2a), R = 2,6-i-Pr-C6H3 (2b), and R = 2,4,6-Me3C6H2 (2c). The X-ray crystal structure of 2c has been carried out. The structure of the diol consists of cyclic hydrogen-bonded dimers linked by further intermolecular hydrogen bonding into a polymeric ribbonlike arrangement.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 8907 |
| Deposited On: | 28 Oct 2010 10:35 |
| Last Modified: | 28 Oct 2010 10:35 |
Repository Staff Only: item control page
