A nonanuclear organostiboxane cage

Chandrasekhar, Vadapalli ; Thirumoorthi, Ramalingam (2009) A nonanuclear organostiboxane cage Organometallics, 28 (8). pp. 2637-2639. ISSN 0276-7333

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Official URL: http://pubs.acs.org/doi/abs/10.1021/om900113q

Related URL: http://dx.doi.org/10.1021/om900113q

Abstract

The first example of a nonanuclear organostiboxane cage, [(Ph2Sb)2(PhSb)7(μ -O)113-O)3(μ -OH)2(μ -cycPO2)2(cycPO2)2(H2O)2]·2CH3CN·H2O, containing Sb(V) has been assembled by a mild hydrolysis and Sb-C bond cleavage reaction of [(Ph3Sb)2(μ -O)(μ -cycPO2)2] (cycPO2 = 1,1,2,3,3-pentamethyltrimethylene phosphinate).

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:8873
Deposited On:28 Oct 2010 10:41
Last Modified:28 Oct 2010 10:41

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