Novel azopyridine-containing silver mesogens: synthesis, liquid-crystalline, and photophysical properties

Sudhadevi Antharjanam, P. K. ; Ajay Mallia, V. ; Das, Suresh (2002) Novel azopyridine-containing silver mesogens: synthesis, liquid-crystalline, and photophysical properties Chemistry of Materials, 14 (6). pp. 2687-2692. ISSN 0897-4756

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Official URL: http://pubs.acs.org/doi/abs/10.1021/cm011730o

Related URL: http://dx.doi.org/10.1021/cm011730o

Abstract

Synthesis, liquid-crystalline, and photophysical properties of a series of novel azopyridine-containing silver complexes have been described. Bis(4-phenyl,4'-azopyridyl)-containing silver complexes exhibiting nematic, smectic, and cholesteric liquid-crystalline phases have been prepared. Photoisomerization of the azopyridyl chromophores in these materials have also been investigated. Glassy solids exhibiting the characterstic iridescent colors as well as Grandjean texture associated with the helical structure of the cholesteric liquid-crystalline phase could be obtained by rapid cooling of the cholesteric liquid-crystalline phases to 0 °C.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:8854
Deposited On:28 Oct 2010 10:44
Last Modified:05 Feb 2011 10:57

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