A novel zwitterionic ortho-metallated ruthenium(II) phenolate

Bag, Nilkamal ; Choudhury, Suranjan Bhanja ; Lahiri, Goutam Kumar ; Chakravorty, Animesh (1990) A novel zwitterionic ortho-metallated ruthenium(II) phenolate Journal of the Chemical Society, Chemical Communications (22). pp. 1626-1627. ISSN 1472-7773

Full text not available from this repository.

Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1990...

Related URL: http://dx.doi.org/10.1039/C39900001626


Decarbonylative metallation of the dialdehyde 2b by [Ru(PPh3)3Cl2] affords the unusual complex [Ru(MeL)(CO)(PPh3)2(Cl)]4 which has been characterised by X-ray crystallography and in which the RuIIP2C2ClO coordination unit bears a single net negative charge; the Ru(MeL)(3, R = Me) fragment incorporates a four-membered C,O-chelated phenolato function with a neighbouring monoprotonated azomethine moiety.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:88440
Deposited On:28 Mar 2012 08:57
Last Modified:13 Jul 2012 13:40

Repository Staff Only: item control page