Chandrasekhar, Vadapalli ; Sasikumar, Palani ; Thilagar, Pakkirisamy (2007) Formation of a double-bicapped hexatin phosphate cage by a de-arylation reaction. Synthesis and structure of [(PhSn)6(μ-OH)2(μ3-O)2(μ-OEt)4{(ArO)PO3}4] (Ar = 2,6-i-Pr2C6H3) Organometallics, 26 (18). pp. 4386-4388. ISSN 0276-7333
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Official URL: http://pubs.acs.org/doi/abs/10.1021/om700421b
Related URL: http://dx.doi.org/10.1021/om700421b
Abstract
The reaction of bis(triphenyl)tin oxide, (Ph3Sn)2O, with 2,6-diisopropylphenylphosphate, (ArO)PO3H2 (Ar = 2,6-i-Pr2-C6H3), leads to the formation of a novel double-bicapped hexanuclear monoorganooxotin cage, [(PhSn)6(μ -OH)2(μ 3-O)2(μ -OEt)4{(ArO)PO3}4]. This reaction proceeds by a de-arylation reaction involving the cleavage of Sn-C bonds.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 8840 |
| Deposited On: | 28 Oct 2010 07:41 |
| Last Modified: | 28 Oct 2010 07:41 |
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