Pardo, Simon N. ; Ghosh, Subrata ; Salomon, Robert G. (1981) Generation of ester enolates by reductive α-deacetoxylation Tetrahedron Letters, 22 (20). pp. 1885-1888. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4039(01)90468-X
Abstract
Diethyl allylmalonates or 2-arylalkanoic esters are prepared in good yield by reductive α-deoxygenation of the corresponding α-acetoxy or α-alkony esters. Since the intermediate ester enolates are generated under aprotic conditions, a one pot reductive-alkylation is also possible. One application of this procedure allows diethyl oxomalonate to serve as a conjunctive reagent for stitching together an alkene and an alkyl halide with a malonyl group as linchpin.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 88019 |
| Deposited On: | 26 Mar 2012 13:52 |
| Last Modified: | 26 Mar 2012 13:52 |
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