Di-tert-butylmethylsilyl (DTBMS) trifluoromethanesulfonate. Preparation and synthetic applications of DTBMS esters and enol ethers

Bhide, Rajeev S. ; Levison, Bruce S. ; Sharma, Ram B. ; Ghosh, Subrata ; Salomon, Robert G. (1986) Di-tert-butylmethylsilyl (DTBMS) trifluoromethanesulfonate. Preparation and synthetic applications of DTBMS esters and enol ethers Tetrahedron Letters, 27 (6). pp. 671-674. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)84069-1

Abstract

DTBMS triflate, readily available from dichloromethylsilane, provides carboxylic esters which resist reduction by hydridoaluminate or acid catalyzed hydrolysis, and vinylogous esters (enol ethers of hydroxymethylene ketones) which resist 1,4-addition of methyllithium.

Item Type:Article
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ID Code:88017
Deposited On:26 Mar 2012 13:52
Last Modified:26 Mar 2012 13:52

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