Maity, Soumitra ; Ghosh, Subrata (2010) An asymmetric route to 2,3-epoxy-syn-1,4-cyclohexane diol derivatives using ring closing metathesis (RCM) Journal of Chemical Sciences, 122 (6). pp. 791-800. ISSN 0377-8444
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Abstract
An asymmetric route for the synthesis of highly functionalized 2,3-epoxy-syn-1,4-cyclohexane diol derivatives present in some polyketide natural products has been developed. The key step involves RCM of an appropriately constructed 1,7-dienol derived from D-mannitol to cyclohexane-1,4-diol followed by its stereoselective epoxidation.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Asymmetric Synthesis; Epoxides; Metathesis; Michael Addition; Natural Products |
| ID Code: | 88001 |
| Deposited On: | 26 Mar 2012 13:55 |
| Last Modified: | 19 May 2016 03:05 |
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