Selvaraj, I. I. ; Reddy, D. ; Vadapalli, Chandrasekhar ; Chadrashekar, Tavarekere Kalliah (1991) Cyclotriphosphazene linked tetraphenylporphyrine Heterocycles, 32 (4). pp. 703-710. ISSN 0385-5414
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Official URL: http://www.heterocycles.jp/index.php
Abstract
Condensation of the functionalised cyclophosphazene aldehyde, N3P3(OC6H5)5(m-OC6H4-CHO)(3) with pyrrole affords the tetraphenylporphyrin (4) containing the cyclophosphazene unit. This has been characterized by spectroscopic and analytical methods. Kinetics of metallation (Cu2+, Zn2+) of (4) indicate slower rates of insertion relative to normal tetraphenylporphyrins. The esr spectrum indicates an axial symmetry for the Cu2+ derivative (6).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Japan Institute of Heterocyclic Chemistry. |
| ID Code: | 87675 |
| Deposited On: | 20 Mar 2012 14:13 |
| Last Modified: | 20 Mar 2012 14:13 |
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