Chandrasekhar, Vadapalli ; Thilagar, Pakkirisamy ; Pandian, Balasubramanian Murugesa (2007) Cyclophosphazene-based multi-site coordination ligands Coordination Chemistry Reviews, 251 (9-10). pp. 1045-1074. ISSN 0010-8545
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00108...
Related URL: http://dx.doi.org/10.1016/j.ccr.2006.07.005
Abstract
This review deals with the recent developments in the design, assembly and utility of cyclophosphazene-based ligands. The reactive periphery of the chlorocyclophosphazenes allows their ready elaboration into a variety of multi-site coordination ligands such as pyrazolylcyclophosphazenes, cyclophosphazene hydrazides, pyridyloxycyclophosphazenes, pyridylaminocyclophosphazenes, phosphine-containing cyclophosphazenes, etc. The versatile coordination behavior of these diverse ligand systems is described. The extension of the small-molecule chemistry to the more complex polymer systems, which has been done in a few systems, is described. The utility of aminocyclophosphazenes for preparing multi-metallic architectures is also discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cyclophosphazenes; Cyclophosphazene Ligands; Multi-Site Coordination Ligands; Polymeric Ligands; Aminocyclophosphazenes; Metal Complexes; Heterobimetallic Complexes |
| ID Code: | 8738 |
| Deposited On: | 28 Oct 2010 10:56 |
| Last Modified: | 28 Oct 2010 10:56 |
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