Enantio-and diastereocontrolled total synthesis of (+)-strictifolione

Kumar, Pradeep ; Pandey, Menaka ; Gupta, Priti ; Vasudeva Naidu, S. ; Dhavale, Dilip D. (2010) Enantio-and diastereocontrolled total synthesis of (+)-strictifolione European Journal of Organic Chemistry, 2010 (36). pp. 6993-7004. ISSN 1434-193X

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ejoc.20...

Related URL: http://dx.doi.org/10.1002/ejoc.201001221


A concise and practical enantioselective synthesis of (+)-strictifolione has been achieved in high diastereomeric excess using Jacobsen's hydrolytic kinetic resolution, proline-catalyzed sequential α-aminoxylation and Horner-Wadsworth-Emmons olefination of aldehyde and cross olefin/ring-closing metathesis as the key steps.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Natural Products; Total Synthesis; Asymmetric Synthesis; Organocatalysis; Ring-closing Metathesis; Hydrolytic Kinetic Resolution; Lactones
ID Code:87227
Deposited On:16 Mar 2012 06:14
Last Modified:19 Mar 2012 11:32

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