Chemistry of tetra- and pentavalent chromium

Nag, Kamalaksha ; Base, Satyendra Nath (1985) Chemistry of tetra- and pentavalent chromium Structure and Bonding, 63 . pp. 153-197. ISSN 0081-5993

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This review provides information on synthesis, reactivities, solid state properties, and electronic and molecular structure of chromium(IV) and chromium(V) compounds that have been isolated in pure form. Spectroscopic properties, especially EPR of Cr5+ and Cr4+ ions doped in various host lattices, are also discussed. However, compounds that generated in solution as transient species, or occured as intermediates in redox reactions, lie outside the scope of discussion. The types of compounds which received major consideration are: oxo-compounds, peroxo complexes, halo and oxyhalo complexes, alkoxides, amides, alkyls, hydroxy carboxylates and macrocyclic compounds. Literature through 1984 is covered. It will be apparent from this article that certain aspects of chromium(IV) and chromium(V) chemistry will get enriched in future.

Item Type:Article
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ID Code:86980
Deposited On:14 Mar 2012 07:31
Last Modified:14 Mar 2012 07:31

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