Linear dependence of spin exchange coupling constant on bridge angle in phenoxy-bridged dinickel(II) complexes

Nanda, Kausik K. ; Thompson, Laurence K. ; Bridson, John N. ; Nag, Kamalaksha (1994) Linear dependence of spin exchange coupling constant on bridge angle in phenoxy-bridged dinickel(II) complexes Journal of the Chemical Society - Series Chemical Communications (11). pp. 1337-1338. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1994...

Related URL: http://dx.doi.org/10.1039/C39940001337

Abstract

A magneto-structural relationship showing linear dependence of antiferromagnetic exchange coupling constant (-J) on Ni-O-Ni bridge angle as well as the intramolecular Ni Ni distance has been obtained with a series of phenoxy-bridged macrocyclic dinickel(II) complexes with centrosymmetric structures.

Item Type:Article
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ID Code:86971
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