Uma, R. ; Rajagopalan, K. ; Swaminathan, S. (1986) Base catalysed rearrangements of oxycope systems Tetrahedron, 42 (10). pp. 2757-2769. ISSN 0040-4020
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)90563-0
Abstract
The synthesis and rearrangements of the chiral carbinols 8 and 9 are described. With KH-THF. both the carbinola gave optically active rearrangement products; with alkali in methanol, they gave optically inactive rearrangement products. The results are interpreted as favouring a concerted mechanism for the hydride catalysed rearrangements and a non-concerted mechanism for the rearrangements catalysed by alkali in methanol.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 86570 |
| Deposited On: | 12 Mar 2012 11:31 |
| Last Modified: | 12 Mar 2012 11:31 |
Repository Staff Only: item control page
