AlB2 to Laves phase transition in ThAl2 under pressure

Godwal, B. K. ; Vijayakumar, V. ; Sikka, S. K. ; Chidambaram, R. (1986) AlB2 to Laves phase transition in ThAl2 under pressure Physica B+C, 144 (1). pp. 44-47. ISSN 0378-4363

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0378-4363(86)90289-5

Abstract

In the structural map for dialuminides based on Miedema parameters, the compound ThAl2, which crystallizes in the AlB2 structure at ambient conditions, falls in the region of Laves phase (MgCu2) compounds. Using four probe electrical resistance and Be gasketed X-ray diffraction measurements, we have shown that only moderate pressure (≈ 0.3 GPa) is required to transform it to the structure predicted by the structural map.

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Deposited On:08 Mar 2012 11:29
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