Kantam, M. L. ; Ramani, T. ; Chakrapani, L. ; Choudary, B. M. (2007) Oxidative kinetic resolution of racemic secondary alcohols catalyzed by resin supported sulfonato-Mn (salen) complex in water Journal of Molecular Catalysis A: Chemical, 274 (1-2). pp. 11-15. ISSN 1381-1169
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.molcata.2007.04.020
Abstract
The oxidative kinetic resolution of racemic secondary alcohols catalyzed by resin supported sulfonato-Mn(salen) complex (R,R)-1 with good to excellent ee's in water in the presence of diacetoxyiodobenzene (PhI(OAC)2) is described. The resin supported (R,R)-1 was recovered quantitatively by simple filtration and reused for three times with consistent activity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Kinetic Resolution; Sulfonato-Mn(Saten) Complex (R, R)-1; Resin; Phi(OAc)2; Enantioselectivity (ee) |
| ID Code: | 86052 |
| Deposited On: | 07 Mar 2012 13:49 |
| Last Modified: | 07 Mar 2012 13:49 |
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