Choudary, B. M. ; Reddy, P. N. (1996) A new alkyl peroxovanadium catalyst for selective oxidation of nitriles to [alpha]-oxo nitriles: a functional mimic of Cyt-P. 450 Journal of Molecular Catalysis A: Chemical, 112 (3). pp. 385-388. ISSN 1381-1169
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Official URL: http://www.sciencedirect.com/science/article/pii/1...
Related URL: http://dx.doi.org/10.1016/1381-1169(96)00147-1
Abstract
Alkyl peroxovanadium complex catalysed functionalisation of methylene of benzyl cyanides to afford peroxo nitriles or aroyl cyanides selectively depending on the molar quantities of oxidant, tert butyl hydroperoxide (t-BuOOH) used is described for the first time.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Alkyl Peroxovanadium Complex; Catalytic Oxidation; Benzyl Cyanides; Aroyl Cyanides; Peroxo Benzyl Cyanides |
| ID Code: | 86021 |
| Deposited On: | 07 Mar 2012 13:44 |
| Last Modified: | 07 Mar 2012 13:44 |
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