Basavaiah, D. ; Pandiaraju, S. ; Krishnamacharyulu, M. (1996) Unprecedented stereochemical reversal from alkyl to aryl substituents in the Johnson-Claisen rearrangement of methyl 3-hydroxy-2-methylenealkanoates Synlett, 1996 (8). pp. 747-748. ISSN 0936-5214
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Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Related URL: http://dx.doi.org/10.1055/s-1996-5524
Abstract
An unprecedented stereochemical reversal from alkyl to aryl substituents in the Johnson-Claisen rearrangement of methyl 3-hydroxy-2-methylenealkanoates with triethyl orthoacetate with a plausible mechanism has been described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | The Johnson-Claisen Rearrangement; The Baylis-Hillman Reaction; Methyl 3-hydroxy-2-methylenealkanoates; (Z)- and (E)-alk-4-enoates |
| ID Code: | 85768 |
| Deposited On: | 06 Mar 2012 04:43 |
| Last Modified: | 06 Mar 2012 04:43 |
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