Oxoanionic or sulfur lone pair attack? The difference in reactivity of hydrogensulfite anion and neutral dimethylsulfite towards [Bu4N]2[MoO2{S2C2(CN)2}2] in the model reductive half reaction of sulfite oxidase

Nagarajan, Kowliki ; Chaudhury, Pradeep K. ; Srinivasan, Bikshandarkoil R. ; Sarkar, Sabyasachi (2001) Oxoanionic or sulfur lone pair attack? The difference in reactivity of hydrogensulfite anion and neutral dimethylsulfite towards [Bu4N]2[MoO2{S2C2(CN)2}2] in the model reductive half reaction of sulfite oxidase Chemical Communications (8). pp. 1786-1787. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2001...

Related URL: http://dx.doi.org/10.1039/B105341H

Abstract

pH dependent reactivity differences of dimethylsulfite towards the title complex 1 demonstrate the crucial need of oxo-anionic coordination of sulfite to the molybdenum centre of 1 in the model reductive half reaction of sulfite oxidase.

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