Effect of environment on the magnetic field modulation of exciplex luminescence

Nath, Deb Narayan ; Chowdhury, Mihir (1984) Effect of environment on the magnetic field modulation of exciplex luminescence Chemical Physics Letters, 109 (1). pp. 13-17. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(84)85391-9

Abstract

The effect of a magnetic field on the pyrene-N,N-dimethylaniline exciplex luminescence in methanol has been studied using an improved phase-sensitive detection technique. The wavelength dependence of B½, the effect of isotopic substitution of the solvent, and the consequences of using mixed donors have been investigated. The results throw light on the environmental perturbation of the intersystem crossing process in solvent-separated radical pairs.

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