Soft-chemical synthesis of new non-linear optical materials, K0.5M0.5Ti0.5OPO4(M = Nb, Ta), related to KTiOPO4

Kasthuri Rangan, K. ; Raghavendra Prasad, B. ; Subramanian, C. K. ; Gopalakrishnan, J. (1994) Soft-chemical synthesis of new non-linear optical materials, K0.5M0.5Ti0.5OPO4(M = Nb, Ta), related to KTiOPO4 Journal of the Chemical Society - Series Chemical Communications (2). pp. 141-142. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1994...

Related URL: http://dx.doi.org/10.1039/C39940000141

Abstract

Soft-chemical oxidation of KTiOPO4-like KMV0.5TiIII0.5OPO4(M = Nb, Ta) using chlorine in CHCl3 is accompanied by partial deintercalation of potassium, yielding K0.5MV0.5TiIV0.5OPO4 compounds which are new non-linear optical materials that exhibit efficient second-harmonic generation of 1064 nm radiation, as does KTiOPO4.

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