Chowdhury, Mihir ; Mukherjee, Ranajit K. ; Bera, Subhas Ch. (1974) The g-value of the 2E state of K3CR(CN)6 and the lower symmetry field Chemical Physics, 3 (3). pp. 482-489. ISSN 0301-0104
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/030101...
Related URL: http://dx.doi.org/10.1016/0301-0104(74)87014-X
Abstract
The 4A2 → 2E transition of potassium chromicyanide has been studied under magnetic field. It has been found that the g-value is nearly isotropic, quite unlike the case of ruby. An attempt has been made to explain the zero-field splittings of 2E, 2T1 and 2T2 states and the g-value of the 2E state on the assumption that the distant ions are mainly responsible for lowering of symmetry of the crystal field from Oh. A reasonable choice of parameters can make the calculated values agree with the observed ones.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 8420 |
| Deposited On: | 26 Oct 2010 12:02 |
| Last Modified: | 04 Feb 2011 04:20 |
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