Nair, V. ; Mathew, J. ; Swaroop Mathen, J. (1997) Cerium(IV) ammonium nitrate mediated addition of ethyl acetoacetate and dimethyl malonate to indene Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 36 (4). pp. 366-368. ISSN 0376-4699
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Abstract
The oxidative addition of ethyl acetoacetate to indene mediated by cerium(IV) ammonium nitrate(CAN) leads to the formation of 2-(2'-indan-1'-one)3-oxobutanoic acid ethyl ester 7 along with two other products, the dihydrofuran 9 and the methyl ester 10. Similar addition of dimethyl malonate to indene gives the indanone 11 and the methyl ether 12. A tentative mechanism which rationalizes the formation of these products is proposed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to National Institute of Science Communication and Information Resources. |
| ID Code: | 84128 |
| Deposited On: | 20 Jun 2012 13:50 |
| Last Modified: | 20 Jun 2012 13:50 |
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