[4+2] Cycloaddition reactions of o-benzoquinones with styrenes: a facile synthesis of bicyclo[2.2.2]octenediones

Nair, Vijay ; Maliakal, Davis ; Treesa, P. M. ; Rath, Nigam P. ; Eigendorf, Guenter K. (2000) [4+2] Cycloaddition reactions of o-benzoquinones with styrenes: a facile synthesis of bicyclo[2.2.2]octenediones Synthesis, 2000 (6). pp. 850-856. ISSN 1570-2693

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-2000-6285

Abstract

o-Benzoquinones undergo facile Diels-Alder reaction with styrenes resulting in a high yield synthesis of bicyclo[2.2.2]octenediones. Rate acceleration of this reaction can be achieved by employing lithium triflate in acetonitrile.

Item Type:Article
Source:Copyright of this article belongs to Bohn Stafleu Van Loghum.
Keywords:Bicyclic Compounds; Cycloadditions; Diels-alder Reactions; Lithium; Quinones
ID Code:84110
Deposited On:24 Feb 2012 06:06
Last Modified:24 Feb 2012 06:06

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