Optical rotatory dispersion of rare earth crystal

Sen, Asok Ch. ; Bera, Subhas Ch. ; Chowdhury, Mihir (1977) Optical rotatory dispersion of rare earth crystal Chemical Physics Letters, 46 (3). pp. 594-596. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(77)80661-1


The ORD spectrum of optically active single crystal of praseodymium oxydiacetate has been studied in the visible range at 77 K. The results have been compared with those obtained in the cases of transition metal complexes and other RE complexes with optically active ligands, and correlated with the site symmetry of the RE ion in the crystal. The optical activity has been related to the magnetic dipole strengths of the transitions.

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