Bulbule, V. ; Deshpande, Vishnu H. ; Velu, Subramani ; Sudalai, Arumugam ; Sivasankar, S. ; Sathe, V.T. (1999) Heterogeneous Henry reaction of aldehydes: Diastereoselective synthesis of nitroalcohol derivatives over Mg-Al hydrotalcites Tetrahedron, 55 (30). pp. 9325-9332. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(99)00494-9
Abstract
Mg-Al Hydrotalcite (HT) has been found to catalyze the reaction between aldehydes and nitroalkanes very efficiently affording threo nitroalkanols in a highly diastereoselective manner. The ratios of three/erythro isomers are determined from their respective 13C-NMR spectra. A mechanism based on the transition state model for the predominant formation of threo-isomers is also described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 83442 |
| Deposited On: | 20 Feb 2012 12:48 |
| Last Modified: | 20 Feb 2012 12:48 |
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