Electrochemically impregnated aluminum-stabilized α-nickel hydroxide electrodes

Dixit, Mridula ; Jayashree, R. S. ; Vishnu Kamath, P. ; Shukla, A. K. ; Ganesh Kumar, V. ; Munichandraiah, N. (1999) Electrochemically impregnated aluminum-stabilized α-nickel hydroxide electrodes Electrochemical and Solid-State Letters, 2 (4). pp. 170-171. ISSN 1099-0062

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Abstract

Nickel-positive electrodes obtained by electrochemical impregnation of aluminum-substituted alpha-nickel hydroxide are found to deliver a reversible discharge capacity of ca. 450 mAh/g. This is much higher than the capacity of beta-nickel hydroxide electrodes [200 mAh/g: this work; 225 mAh/g: Dixit et al., J. Power Sources, 63, 167 (1996)] prepared under identical conditions and pasted electrodes comprising cobalt-doped nickel hydroxide [345 mAh/g: Faure et al., J. Power Sources, 36, 497 (1991)]. These observations suggest that the theoretical target-capacity for high-performance nickel-positive electrodes must be revised from the currently accepted value of 289 mAh/g (le exchange) to 491 mAh/g [1.7e exchange.

Item Type:Article
Source:Copyright of this article belongs to The Electrochemical Society.
ID Code:83232
Deposited On:17 Feb 2012 04:30
Last Modified:17 Feb 2012 04:30

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