Mathu, Pradeep ; Dash, Aswini K. ; Munki Hossain, Md. ; Satyanarayana, C. V. V. ; Verghese, Babu (1996) A chalcogen-stabilized cluster containing a s-trans-1,3-diene ligand: synthesis and structural characterization of {(CO)6Fe2Se2}2(μ-s-trans-C4H2) Journal of Organometallic Chemistry, 506 (1-2). pp. 307-312. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-328X(95)05749-F
Abstract
Reaction of (CO)6Fe2(μ-Se)2 with HC=CC=CR (R = Sime3 or SnnBu3) at room temperature in methanol containing sodium acetate yielded the unexpected product {(CO)6Fe2Se2}2(μ-s-trans-C4H2) in which a 1,3-butadiene ligand is coordinated to Fe2Se2 core in a trans conformation as determined by a single-crystal X-ray diffraction studies. The complex was also obtained with a low yield by reaction of (CO)6Fe2(μ-Se)2 with HC=CC=CH under similar conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Iron; Carbonyl; Cluster; Butadiene; Selenium; Crystal Structure |
| ID Code: | 83053 |
| Deposited On: | 16 Feb 2012 04:20 |
| Last Modified: | 16 Feb 2012 04:20 |
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