Mathur, Pradeep ; Munkir Hossain, Md. ; Rheingold, Arnold L. (1996) Diacetylene-bridged clusters: synthesis and characterization of (CO)6Fe2Se2{μ-HC=C(C=CR)}, {(CO)6Fe2Se2}2{μ-HC-C(C=CR)} (R=Me on n-Bu) and (CO)6Fe2Se2(μ-HC=CC=CCH3 OS3(CO)10 Journal of Organometallic Chemistry, 507 (1-2). pp. 187-195. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-328X(95)05727-7
Abstract
The compounds (CO)6Fe2Se2{μ-HC=C(C=CR)} (R=Me (1) or n-Bu (2) and {(CO)6Fe2Se2}2{μ-HC=C(C=CR)} (R=Me (3) or n-Bu (4)) have been obtained by room-temperature reactions of Fe2(CO)6(μ-Se2) with HC-CC-CR. Compound1 Os3(CO)10(NCMe)2 to give (CO)6Fe2Se2(μ-HC=CC=CCH3OS3(CO)10 (5). The structure of compounds 1, 3 and 5 have been established by single-crystal X-ray diffraction studies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Iron; Carbonyl; Alkyne; Clusters; Crystal Structure |
| ID Code: | 83052 |
| Deposited On: | 16 Feb 2012 04:20 |
| Last Modified: | 16 Feb 2012 04:20 |
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