Chakrabarty, Debojit ; Munkir Hossain, Md. ; Krishna Kumar, R. ; Mathur, Pradeeb (1991) Mixed chalcogen carbonyl compounds: II. Synthesis and characterization of Fe2Ru(μ3-Se)(μ3-Te)(CO)9 and (μ5-C5H5)CoFe2(μ3-Se)(μ3-Te)(CO)6 Journal of Organometallic Chemistry, 410 (2). pp. 143-148. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-328X(91)80003-3
Abstract
The new mixed metal complexes, each containing bridging selenium and tellurium ligands in the same molecule, Fe2Ru(CO)9(μ3-Se)(μ3-Te) and (η5-C5H5)CoFe2(CO)6(μ3-Se)(μ3-Te) have been prepared from the room temperature reactions of Fe2(CO)6(μ-SeTe) with Ru(CO)4(C2H4) and (C5H5)Co(CO)2, respectively. Reaction of (η5-C5H5)CoFe2(CO)6(μ3-Se)(μ3-Te) with Pt(PPh3)4 forms the previously known (CO)6Fe2(μ3-Se)(μ3-Te)Pt(PPh3)2 and on treatment with NaOMe, followed by acidification, Fe2(CO)6(μ-SeTe) is formed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 83045 |
| Deposited On: | 16 Feb 2012 04:19 |
| Last Modified: | 16 Feb 2012 04:19 |
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