Addition of methylene groups to Fe3(CO)93-Te)2

Mathur, Pradeep ; Dayal Reddy, V. ; Bohra, Rakesh (1991) Addition of methylene groups to Fe3(CO)93-Te)2 Journal of Organometallic Chemistry, 401 (3). pp. 339-346. ISSN 0022-328X

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At room temperature, Fe3(CO)9(μ-Te)2 reacts with diazomethane to form (CO)6Fe2(μ-TeCH2Te) (I) and (CO)6Fe2Te2(CH2)2 (II). Complexes I and II have been separated by chromatography and characterised by IR and NMR spectroscopy, mass spectrometry and microanalysis. Complex I was also subjected to an X-ray diffraction study. The crystals are monoclinic, space group P21/c with a = 6.864(2), b = 13.926(3), c = 14.159(3) Å, β = 104.43(2)°, V = 1310.6(5) Å, Z = 4, Dc = 2.79 g cm-3 and R = 0.043.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:83043
Deposited On:16 Feb 2012 04:18
Last Modified:16 Feb 2012 04:18

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