Mathur, Pradeep ; Mavunkal, Ipe J. ; Rugmini, Varikkat (1989) The contrasting roles of the various chalcogens in the synthesis of mixed metal complexes (CO)6Fe2(μ3-E)2M(PPh3)2 (E = Te, Se, S; M = Ni, Pd, Pt)) Journal of Organometallic Chemistry, 367 (1-2). pp. 243-248. ISSN 0022-328X
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-328X(89)87222-5
Abstract
Reactions of Fe3E2(CO)9 (E = S, Se) with M(PPh3)4 (M = Ni, Pd, Pt), at room temperature, show a marked contrast with the analogous reaction of Fe3Te2(CO)9. Different mechanisms are suggested for the formation of the mixed-metal complexes, Fe2E2(CO)6M(PPh3)2 (E = S, Se, Te; M = Pd, Pt, and E = Te; M = Ni), depending on the chalcogen atom involved. The size of the chalcogen and that of the heterometal atom play crucial roles in the outcome of the reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 83039 |
| Deposited On: | 16 Feb 2012 04:17 |
| Last Modified: | 16 Feb 2012 04:17 |
Repository Staff Only: item control page
