Bond length and bond multiplicity: σ-bond prevents short π-bonds

Jemmis, Eluvathingal D. ; Pathak, Biswarup ; Bruce King, R. ; Schaefer III., Henry F. (2006) Bond length and bond multiplicity: σ-bond prevents short π-bonds Chemical Communications, 2006 (20). pp. 2164-2166. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2006...

Related URL: http://dx.doi.org/10.1039/B602116F

Abstract

Analysis of model compounds such as Fe2(CO)6, C2 and HBBH shows that π-bonds left to themselves are shorter than σ-bonds; in many ways σ-bonds prevent π-bonds from adopting their optimal shorter distances.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:82706
Deposited On:14 Feb 2012 11:46
Last Modified:14 Feb 2012 11:46

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