Theoretical studies of (μ-CR) bridging complexes

Jemmis, Eluvathingal D. ; Prasad, Bharatam V. (1988) Theoretical studies of (μ-CR) bridging complexes Polyhedron, 7 (10-11). pp. 871-879. ISSN 0277-5387

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Scrambling of substituents on the C3R3 bridging ligands in L2W(μ-C3R3)(μ- CR)WL2 is studied using Extended Hückel calculations by two pathways: deinsertion and cyclopropenium ring formation. The reaction of L2W(μ-CR)2WL2 with allenes to give L2W(μ-CHC(CR2)2)(μ-CR)WL2 is also studied. The electronic structure of CpMeW(μ- CMe)2WMeCp is compared to that of L2W(μ-CR)2WL2.

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ID Code:82672
Deposited On:14 Feb 2012 11:18
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