AC impedance behaviour and state-of-charge dependence of Zr0.5 Ti0.5V0.6Cr0.2Ni1.2 metal-hydride electrodes

Rodrigues, S. ; Munichandraiah, N. ; Shukla, A. K. (2001) AC impedance behaviour and state-of-charge dependence of Zr0.5 Ti0.5V0.6Cr0.2Ni1.2 metal-hydride electrodes Proceedings of the Indian Academy of Sciences - Chemical Sciences, 113 (5-6). pp. 527-537. ISSN 0253-4134

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Official URL: http://www.ias.ac.in/chemsci/Pdf-OctDec2001/Pc3094...

Related URL: http://dx.doi.org/10.1007/BF02708788

Abstract

Metal-hydride electrodes made of an AB2 alloy of the composition Zr0.5 Ti0.5 V0.6 Cr0.2 Ni1.2 are studied for AC impedance behaviour at several of their state-of-charge values. Impedance data at any state-of-chargecomprisetwo RC-time constants and accordingly are analysed by using a nonlinear-least-square-fitting procedure. Resistance of the electrode and frequency maximum (f) of the lowfrequency semicircle are found useful for predicting state-of-charge of the metalhydride electrodes.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
Keywords:Hydrogen-storage Alloy; Metal-hydride Electrode; AC Impedance; AB2 Alloys; State-of-charge
ID Code:81847
Deposited On:07 Feb 2012 11:26
Last Modified:18 May 2016 23:15

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