A novel approach for estimating the electrode kinetic parameters of gas-diffusion electrodes using the inflection point in steady-state current/potential data

Sugumaran, Nanjan ; Shukla, A. K. (1992) A novel approach for estimating the electrode kinetic parameters of gas-diffusion electrodes using the inflection point in steady-state current/potential data Journal of Power Sources, 39 (2). pp. 249-254. ISSN 0378-7753

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0378-7753(92)80144-Z

Abstract

A method is proposed for deriving electrode kinetic parameters (i.e., Tafel slopes, exchange-current densities and limiting currents) using the inflection point in steady-state current/potential data, without reaching the limiting-current region. The procedure is applied to the oxygen reduction reaction on a Nafion-bound platinized carbon electrode, a CoTMPP (cobalt tetramethoxyphenylporphyrine) catalyzed carbon electrode, and a pyrochlore oxide based electrode.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:81740
Deposited On:07 Feb 2012 11:26
Last Modified:07 Feb 2012 11:26

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