Electron-transfer distance in intermolecular diffusion-limited reactions

Dutt, G. B. ; Periasamy, N. (1991) Electron-transfer distance in intermolecular diffusion-limited reactions Journal of the Chemical Society, Faraday Transactions, 87 (24). pp. 3815-3820. ISSN 0956-5000

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1991...

Related URL: http://dx.doi.org/10.1039/FT9918703815

Abstract

Diffusion-limited fluorescence quenching of ZnTPP(1S1) and quinone (benzoquinone BQ and chloranil CA) have been studied in toluene and acetonitrile at 5, 25 and 45 ° C. The steady-state and time-domain experimental studies indicate that the 'optimum' electron-transfer distance is larger by 3-5 Å for the ZnTPP-CA reaction than that in the ZnTPP-BQ reaction.

Item Type:Article
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ID Code:81716
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