Electrochemical phase formation (ECPF): nucleation growth vis-a-vis adsorption models

Bosco, E. ; Rangarajan, S. K. (1981) Electrochemical phase formation (ECPF): nucleation growth vis-a-vis adsorption models Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 129 (1-2). pp. 25-51. ISSN 0022-0728

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0022-0728(81)80003-4

Abstract

The nucleation growth model of electrochemical phase formation is analysed for the linear potential sweep input. Apart from deducing diagnostic criteria and methods of estimating model parameters, the predictions of the nucleation growth model are compared and contrasted with those of a simple adsorption model. A distinction is made possible between adsorption and phase transition, which seems useful for understanding the nature of ECPF phenomena, especially underpotential deposition (UPD).

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:81255
Deposited On:07 Feb 2012 05:05
Last Modified:07 Feb 2012 05:05

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