Mishra, A. K. ; Rangarajan, S. K. (1987) Theory of electron-transfer processes via chemisorbed intermediates Journal of Physical Chemistry, 91 (12). pp. 3417-3425. ISSN 0022-3654
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/j100296a062
Related URL: http://dx.doi.org/10.1021/j100296a062
Abstract
A model Hamiltonian to describe adsorbate-mediated electron transfer is proposed and analyzed for the (electrochem.) currents. This Hamiltonian differs fundamentally from the ones used earlier (cf. Schmickler 1980, 1982). Three situations are treated, viz., (1) a lone adsorbate picture; (2) presence of an inactive neighboring adsorbate; and (3) electrostatic effects due to an adsorbate lattice. In all 3 cases, the mediation is via a single adsorbate only. Several limiting cases are considered and related to the earlier results of Marcus and Schmickler.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 81232 |
| Deposited On: | 04 Feb 2012 12:36 |
| Last Modified: | 04 Feb 2012 12:36 |
Repository Staff Only: item control page
